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Study of glyphosate degradation in water plasma application
Vašinková, Alena ; Vávrová, Milada (referee) ; Mravcová, Ludmila (advisor)
This work deals with the current problem of increasing concentrations of glyphosate in groundwater and wastewater due to insufficient efficiency of methods used in wastewater treatment. From this point of view effective removing of glyphosate from water have to be developed by new methods and technological processes. The methods used so far in wastewater treatment plants should be replaced or supplemented by advanced oxidation processes. The practical part of this work is devoted to glyphosate and its degradation in water by plasma. Samples were taken sequentially during plasma application and further evaluated by LC/MS selected as suitable analytical methods. The aim of this work was to determine the efficiency of plasma in water with admixture of glyphosate.
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Pesticide glyphosate and possibilities of its determination
Stará, Kristýna ; Mravcová, Ludmila (referee) ; Řezáčová, Veronika (advisor)
This bechelor thesis deals with determination of glyphosate employing capillary isotachophoresis technique. The literature review is devoted to pesticide, their distribution and use, properties and methods for the glyphosate determination, capillary zone isotachophoresis and its use. Experimental part focuses on the application of capillary isotachophoresis for determination of glyphosate, for determination of glyphosate in commercial preparations and testing of glyphosate sorption in soil.
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Vliv glyfosátu na fyziologické procesy v živočišném organismu
Jelínková, Lucie
This bachelor thesis deals with the effect of glyphosate on the animal organism. The influence of individual selected groups of animals and humans is examined in different types of expermients. The bees in the behavioral study showed a reduced response to sucrose, a deterioration in short-term memory and a deterioration in the formation of ofor-foos relationships. Glyphosate reduced biodiversity in the amphibian population and also halved the toxicity at lower doses when the active substance was studied. Glyphosate also affects carp hepatocytes, which are subject to histological changes. The deteriorating health of the fish, which is infested with exoparasites, makes it easier for glyphosate to enter the body. In rats and rabbits, they cause reproductive problems. Human placental cells respond to glyphosate by reducing the production of the enzyme responsible for estrogen synthesis and thus to fertility problems. Glyphosate is more common in professional exposure and i tis similar in the population living in the immediate vicinity of its application.
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Pesticide glyphosate and possibilities of its determination
Stará, Kristýna ; Mravcová, Ludmila (referee) ; Řezáčová, Veronika (advisor)
This bechelor thesis deals with determination of glyphosate employing capillary isotachophoresis technique. The literature review is devoted to pesticide, their distribution and use, properties and methods for the glyphosate determination, capillary zone isotachophoresis and its use. Experimental part focuses on the application of capillary isotachophoresis for determination of glyphosate, for determination of glyphosate in commercial preparations and testing of glyphosate sorption in soil.
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Study of glyphosate degradation in water plasma application
Vašinková, Alena ; Vávrová, Milada (referee) ; Mravcová, Ludmila (advisor)
This work deals with the current problem of increasing concentrations of glyphosate in groundwater and wastewater due to insufficient efficiency of methods used in wastewater treatment. From this point of view effective removing of glyphosate from water have to be developed by new methods and technological processes. The methods used so far in wastewater treatment plants should be replaced or supplemented by advanced oxidation processes. The practical part of this work is devoted to glyphosate and its degradation in water by plasma. Samples were taken sequentially during plasma application and further evaluated by LC/MS selected as suitable analytical methods. The aim of this work was to determine the efficiency of plasma in water with admixture of glyphosate.
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Silver Amalgam Electrodes in Electroanalysis of Selected Agrochemicals
Daňhel, Aleš ; Barek, Jiří (advisor) ; Vytřas, Karel (referee) ; Ludvík, Jiří (referee)
4 ABSTRACT Development and testing of novel non-toxic electrode materials, detection arrangements and analytical methods applicable in determination of selected agrochemicals is the main aim of this Ph.D. Thesis. New working electrodes based on silver solid amalgam paste (AgSA-PE) with organic pasting liquid and other based on crystallic silver amalgam (CAgAE) were developed, their electrochemical behaviour investigated and further used in voltammetric determination of widespread and toxic environmental pollutant 4-nitrophenol (4-NP). This analyte could be determined by DPV at AgSA-PE with limit of detection (LD) 1×10í6 mol lí1 and using CAgAE with LD 4×10í7 mol lí1 , both in 0.2 mol lí1 acetate buffer pH 4.8. Attempts to decrease LDs by utilization of adsorptive stripping voltammetry were not successful in either case. Crystallic silver amalgam was also successfully used for construction of microcylindric flow-through cell and tested for amperometric determination of nitrophenol mixture in HPLC-ED system. Both novel electrodes were found to be suitable alternatives to toxic mercury electrodes and the CAgAE seems to be promising working electrode for flowing systems. Method for sample preparation and voltammetric determination of broad-spectrum herbicide Glyphosate in contaminated soil samples was also...
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Mechanical and chemical control of perennial weed
ŠMÍDA, Petr
Perennial weed creeping thistle and couch-grass were controlled for tree year period in Prepychy village (Rychnov nad Kneznou district). Stubble breaking had cardinal effect on regeneration of hypogenous vegetative organs both wedd and endorsed their appearance. Following ploughing and ground reproduction before seeding didn´t control these weed. In chemical control section was tested an effectiveness of 22 herbicides. Creeping thistle showed the highest sensitivity against the majority of herbicides in growth phase F4 (stalk height 20 cm). Results of experiments showed an importance of application a.i. glyphosate in perennial weed control system. In winter wheat vegetation showed herbicides Husar and Lontrel 300 the highest effect against creeping thistle. Broad-leaved crops give a possibility to use graminicides against couch-grass. Graminicides Fusilade Forte 150 EC and Gallant Super shown the highest effect against couch-grass.
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